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This effect is activated when a Synchro Monster is Special Summoned, not a Synchro Summon , so this includes when the opponent summons a Synchro Monster, and it is activated not only for Synchro Summons but also for other special effects

Its worth noting that I open these things a lot

It also works well alongside a Pokmon booster box protector in mixed display setups

You can only activate this card when your opponent's hand is 6 or more cards and your hand is 2 or less

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This card is mostly used as a means of countering popular hand traps like Ash Blossom & Joyous Spring and Infinite Impermanence